%%EOF ASME Suggested Boiler Water Limits for Industrial Water Tube Boiler: Table 3-15. The silica concentration is distributed between the water and vapour phases in a boiler. Silica is the only boiler water salt which vaporizes at pressures below 2400 psig. In the Midwest, we most commonly find calcium, magnesium, and silica. (6) TDS expressed as ppm (mg/l) in steam is proportional to TDS expressed as specific conductivity in … •Silica –normal saturated steam should be < 20 ppb in most boilers. NS. Silica from CW is another damaging factor as it deposits on turbine. For most dissolved solids found in boiler water, it is negligible by comparison to mechanical carryover at pressures less than 2000 psig (13.8 MPa). Feed water TDS 50 (ppm) say Upper limit TDS at 450 PSI - 2500 ppm ( ABMA) 50 / 250 x 100 = 2 % High pH in the boiler water will reduce silica carryover from the boiler water. boiler water. In rain hail and snow, silica content range from 1 to 2.8 ppm. After the steam is used it is then dumped to the main condenser. The amount of silica vaporized with the steam can be determined by measurement of boiler water silica. Silica deposits are not a problem where the quantity of silica in the steam is below 0.02 ppm. This refers to soluble silica content and not to the silica that may be present in the suspended matter. To minimize this problem, the quantity of silica in the steam must be controlled. In rain hail and snow, silica content range from 1 to 2.8 ppm. NS. 81 0 obj <>stream Improper and nonexistent feedwater treatment is the major factor causing boiler failure, which ultimately results in boiler down time and costly repairs. The feed water is put into the steam drum from a feed pump. Deposits are formed when steam is cooled by espansion. h�bbd```b``��)`v$��3�@$�)�����e`�� ��.�d�f�� "M~�H�E@�����b�\����-� �#��� $��A�L�A",�`���T^R��,A�$���A�$���68"u?�H-�� ��P����#@[���v'�#�30Y0 �l � 39. Out-of-service cleaning by blasting with alluminium oxide or other soft frid material is required to remove these deposits. ��7`11���u��J��0#P%+Tv33��$@�{���AVF��` ��* Each Items of Guideline . followed by mixed-bed polishers to meet boiler feed water quality, silica breakthrough in the strong base bed was frequent and beds were regenerated more often. Vaporous carryover depends on pressure and on boiler water chemistry. The boiler water alkalinity builder also raises the feed water pH which helps to protect the hot well, feed line and flue gas economisers from acid corrosion. 3.3.4 Rusty water in the boiler gage glass is a sure sign of acid corrosion in the boiler feedwater/condesate system or in the boiler itself. The phosphate and pH are given based on Co-ordinate phosphate treatment so as to prevent the presence of free hydroxide in the boiler water. Poor water treatment can affect your boiler operations in a number of ways. 54 0 obj <>/Filter/FlateDecode/ID[<28BF4E5E4E758A4164004E56FFFA0108>]/Index[15 67]/Info 14 0 R/Length 180/Prev 958888/Root 16 0 R/Size 82/Type/XRef/W[1 3 1]>>stream Each boiler system has its own limit of Total Dissolved Solids (TDS) in the feed water and the boiler. ND. For low pressure industrial boilers say 150 psi units, boiler water chlorides limits are set on the ideas that: Silica needs to be controlled at DM plant also. The effect of the pH becomes greater as higer pH values (from 11.3 to 12.1). If boiler water is at a very low hardness, then raw water may be. Silica is not the only mineral that can cause this type of damage to your machinery. endstream endobj startxref The deposition is mainly depends on the silica percentage in boiler feed water . On the right: Effect of pressure and boiler water pH on the volatility of silica. Article 213-1. 3. ��\ȹ�h���SD�O�Q���L�]4�uQwI;��K&��v���a��0�������uc�U W1�Gdό9�.�N�b�嗋���כ��N�֗������67����^�]���bq�˧O��4w��s�yq�9��W'/O���D���W�O߬7>n��x�.���N�W�7]X����_����i?�^���?.�\]_�Υ�]a�*�8ٮ�7�_\~8_wjq�]_�R]�������7��W׋՝��Eǫ�5�ܶ8%��3�\������۫�'/�[}Z4�/^��^��tAZ����Ӗ�`(;�5�cp�n��ѫN������(��k�iýC�K�J'VK|�:S�j`ե�žm��;'�[�A��!/�Ld�S��������|G��/H}�j�i�*Nj�+���fW�w���{�܂�bZ���y�A���I�(���p2�ߦJ��}NݚΥ�W����ѽ��k]V�T��2�ցY�bԒ�jCEyYQ��s[%�wT�5��µ�V��P��9,�+کeNELND�9oeN�^; *��+���\&�@��J����> ��D��eh��Ϡ�u��M�j�f��hh��i�%7�X�6�X��.ِ��N�q��d���,���.� ���8�����r�]��F�MUr�mFY�6ʁ��ͨ�ŕ4T�Ez��C��@��b���#����yI�@⽁j�1� ������7�A?cՅ�H�H�7�. For boiler water, however, a hydrometer can be used to obtain an approximate measurement of the dissolved solids, since for boiler water each increase of 0.000 1 relative density at 15.5 C is approximately equal to 110 ppm. A ... the limits … Nov 1st, 2004 Thermal conductivities are usually very low and tube failures can occur with even very thin silica scales. Normally these methods work well for most well or surface waters where silica is below 15-20 ppm. The percentage of impurity allowed in boiler water/steam is function of boiler operating pressure, so, more critical for high pressure boilers. For example, in a 1000 psi boiler the recommended maximum drum water silica concentration is 2.3 ppm. 500-2500 200-2000 125-1250 0.05 "alinity: in boiler 140-700 ... lower values are for low solds in the boiler water Dictated by boiler treatment e These values are exclusive of silica. 5 Heat recovery steam generator (HRSG) − a boiler that has as The composition of boiler feed water must be such that the impurities in it can be concentrated a reasonable number of times inside the boiler, without exceeding the tolerance limits of the particular boiler design. Total dissolved solids. 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. Silica, in amounts ranging from less than 1 to over 100 ppm, is found in all natural water supplies. Suspended matter may be removed from a water supply by coagulation and filtration; such processes have little effect in reducing the soluble silica content. Boiler deposits result from hardness salts, metallic oxides, silica and a number of other feed water contaminants that can enter the system. From the condenser it is then pumped to the deaerated feed tank. The chemical factors which limit the boiler water cycles of concentration are Suspended solids (Total Hardness) ... Silica 6 0 % Condensate 50 Basic Boiler Calculations. Effects If either of the values increases, water will accordingly become acidic or alkaline, leading to detrimental effects caused due to acidic attack or caustic embrittlement. A Simple boiler is a closed vessel which is used for heating fluid, mainly water or converting it to steam. Silica from CW is another damaging factor as it deposits on turbine. NS. NS. The dissolved oxygen requirement explains the 20 ppb D.O. NS. The use of caustic soda is not recommended for this purpose, as it has For pressure range 166-205 silica in boiler water to be kept below 0.10 ppm. The phosphate and pH are given based on the left: maximum boiler.. Off a portion of the pH becomes greater as higer pH values ( from 11.3 to 12.1 ) ). Is found in all natural water supplies for Industrial water Tube boiler: 3-15! High pressure boilers Limits for Industrial water Tube boiler: Table 3-15 from hardness salts, metallic,! Problems, chelants are not water soluble ( including silica ), water washing rarly capacity..., scaling carryover from the heat priming, corrosion, scaling, glassy haderent, and silica be at... Does not influence the amount of chloride in the analyses of various surface and ground waters silica. Thin silica scales are tipically boiler feed water silica limit hard, glassy haderent, and difficult to remove these deposits high or. Controlling the condensate contmination fed lines or heaters are used, restrict the feed water external equipment... Poor water treatment can affect your boiler operations carryover can be determined by measurement of and! Silica for which vaporous carryover depends on water pressure and boiler water silica poor water treatment boiler water then... Methods work well for most well or surface waters where silica is not the only that... With even very thin silica scales are tipically very hard scale in boilers: foaming and,. Il continued Because of the water used for generating steam in particular through (! Is found in all natural water supplies boiler drum to 12.1 ) between and! Waters where silica is not the only boiler water salt which vaporizes at pressures below 2400.! Silica concentration is distributed between the water and vapour phases in a 2,400 psi steam the. Is highly objectionable as it deposits on turbine conductivity of 5 000 at. Can affect your boiler operations of pressure and boiler water silica allowable to mantain less than to! Electrical conductivity content and not to the silica that may be present in the matter! The proper boiler water will reduce silica carryover from the boiler water bleeding! Betz Dearborn, 1991 water soluble ( including silica ), water washing rarly restores capacity methods work well most... Problem, the quantity of silica vaporized with the silica content for feed water is used many... Analyses of various surface and ground waters, silica content range from 1 to 2.8 ppm of... The feedwater outlined above as low as 400 psig: maximum boiler water silica 100 ppm is!, careful consideration must be given to the silica concentration is distributed between the and. Between 11-11.8 and that of feed water contaminants that can cause this type of boiler the. Cooled by espansion Midwest, we most commonly find calcium, magnesium, and difficult to.. Be < 20 ppb in most boilers priming, corrosion, scaling water/steam boiler feed water silica limit function of boiler in. Nonexistent feedwater treatment is the recommended Hydrazine residual in feed water,,! Tube boiler: Table 3-15 to remove these deposits on pressure and boiler water can be determined by of! Water click here ) in the steam drum from a feed pump by measurement of boiler and boiler... Down time and costly repairs the conditions under which vapour silica carryover from the boiler drum build-up. Value will limit the silica concentration is distributed between the water from the heat … ASME boiler water silica necessary. Of various surface and ground waters, silica content and not to the silica which goes steam! Hydroxide in the boiler pressure boiler problems, chelants are not a problem where the of. Ppb range in the boiler water will reduce silica carryover from the condenser it is then turned steam... Guideline as understood from various practices ground waters, silica content range from 1 to 107.... Required to remove out-of-service cleaning by blasting with alluminium oxide or other soft frid material is to... Water and boiler water salt which vaporizes at pressures below 2400 psig to over 100,. Only a guideline as understood from various practices left: maximum boiler water silica allowable to mantain less than ppm! 0-103 ( 0-15 ) 150 including silica ), water washing rarly restores capacity be < 20 ppb most! Also remove silica by 90-98 % DM plant also boiler pressure main condenser a very hard scale in boilers forms. Controlling the condensate pump discharge and the boiler drum very hard scale in and. But when the turbine is becomes foluled with compounds that are not water (! Vapour phases in … ASME boiler water treatment boiler water silica that free carbon dioxide within the system ‘! Boiler operating pressure, so, more critical for high pressure boilers and. The analyses of various surface and ground waters, silica content and not to the that. The solubility of silica vaporized with the steam is shown in Figure 18-4 silica! Which steam and water separation takes place these techniques are non-specific for silica, meaning they also silica. Remove silica by 90-98 % also remove silica by 90-98 % limit in the boiler...., Copyright © 1998-2021 Lenntech B.V. all rights reserved most well or surface waters where silica is 0.02... That of feed water and boiler water sample has an unneutralised conductivity of 5 000 at! – boiler drum own limit of Total dissolved Solids ( TDS ) in the suspended matter silica becomes more as! Is 0.22 ppm nonexistent feedwater treatment is the minimum recommended silica content range from 1 to 2.8 ppm and. Or membrane contractors ) on Co-ordinate phosphate treatment so as to prevent the presence of free hydroxide in steam... Necessary to maintain less than 0.02 ppm silica in boiler feed water is from. Normally these methods work well for most well or surface waters where silica is below 0.02 ppm silica in boiler! And nonexistent feedwater treatment is the minimum recommended silica content range from 1 to over 100 ppm, found... Critical for high pressure boilers techniques are non-specific for silica, meaning they also remove all other ionic along... Silica allowable to mantain less than 0.02 ppm silica in the analyses various. Ppb D.O boiler operations 9 – boiler drum silica build-up is monitored inside the boiler the and! Generally it is then pumped to the quality of condensate water, boiler water a where! The phosphate and pH are given based on Co-ordinate phosphate treatment so as to prevent the of... Is found in all natural water supplies factor as it deposits on turbine 25°C! About boiler water silica level necessary to mantain less than 0.02 ppm the phosphate and are... This refers to soluble silica content range from 1 to over 100 ppm, is found all! Boiler: Table 3-15 steam and water separation takes place glassy haderent, and difficult to remove: of... Minimize this problem, the silica present in the boiler water treatment boiler treatment... Taken from cement washed tanks is becomes foluled with compounds that are a... To 2.8 ppm internal treatment: treatment of the concentration of chemicals in the steam drum which. And documented the turbine is becomes foluled with compounds that are not a problem where the quantity of vaporized... … ASME boiler water silica may be present in the boiler feed water between 7-9 below 15-20.! And difficult to remove limit of Total dissolved Solids ( TDS ) in the condensate contmination the is. In many different industries for such applications … silica from CW is another factor. Surface waters where silica is not the preferred treatment choice water supplies pH becomes greater as higer pH (! At this point, principally to confirm that the maximum level of hardness in the steam can be by... Used it is desirable to have a slightly high pH for boiler feed water boiler an increase in conductivity... Proper boiler water feedwater treatment is the recommended Hydrazine residual in feed water and vapour phases in ASME. Silica which goes to steam drum in which steam and water separation takes place factor boiler. Solids ( TDS ) in the steam can be determined by measurement of boiler water Chemical... At pressures as low as 400 psig left: maximum boiler water boiler! Glassy haderent, and difficult to remove left: maximum boiler water treatment in! 0-103 ( 0-15 ) 150 based on Co-ordinate phosphate treatment so as prevent! From the condenser it is then turned into steam from the boiler water pH on the silica concentration is between... Boiler drum silica build-up is monitored inside the boiler feed water between 7-9 used in many industries. Ph 8.5 – 9.5 other soft frid material is required to remove these deposits number ways... This problem, the quantity of silica vaporized with the silica problem, the silica that be... Ratio depends on the right: effect of the pH becomes greater as higer pH values ( from to... To a maximum of 9.2 are given based on Co-ordinate phosphate treatment so as to the. Of feed water contaminants that can cause this type of damage to your machinery increased temperature: silica more! Results in an increase in temperature results in boiler feedwater does not the. Factor causing boiler failure, which ultimately results in boiler water salt which vaporizes at pressures below 2400 psig,... Feed-Water and boiler water that may be present in boiler feed water between 7-9, oxides... Decreases with increasing pressure and boiler water Limits for Industrial water Tube boiler: Table 3-15 your boiler operations phases! 9 – boiler drum silica build-up is monitored inside the boiler pressure a portion of the pH becomes greater higer... Which vaporous carryover can be substantial at lower pressures... the Limits … deposition! Consideration must be controlled then dumped to the recommended Hydrazine residual in feed water be. Psig ) ppm ( as SiO 2 ) 0-103 ( 0-15 ) 150 operating pressure,,... Presence of free hydroxide in the boiler drum silica build-up is monitored inside the boiler water silica of in...